Markovnikov-Selective Hydroboration of Unactivated Alkenes via MHAT under Cobalt/Photoredox Dual Catalysis

Key Points

• To develop a method for Markovnikov-selective hydroboration of unactivated alkenes using dual catalysis.
• Employ Markovnikov-selective hydroboration using MHAT
• Utilize cobalt and photoredox dual catalysis
• Investigate the reaction across mono-, di-, and trisubstituted alkenes
• Achieve high regioselectivity in hydroboration
• Generate alkyl boronic esters from unactivated alkenes
• Utilize radical intermediates to facilitate the reaction

Abstract