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For stochastic nonequilibrium dynamics like a Langevin equation for a colloidal particle or a master equation for discrete states, entropy production along a single trajectory is studied. It involves both genuine particle entropy and entropy production in the surrounding medium. The integrated sum of both Delatas(tot) is shown to obey a fluctuation theorem (exp([-Deltas(tot) = 1 for arbitrary initial conditions and arbitrary time-dependent driving over a finite time interval.
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Udo Seifert (Wed,) studied this question.
www.synapsesocial.com/papers/69d7599fb4cef8fedc48f709 — DOI: https://doi.org/10.1103/physrevlett.95.040602
Udo Seifert
Physical Review Letters
University of Stuttgart
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