This study investigates the heterogeneity of pore structures in lacustrine shale gas reservoirs, with a specific focus on shales from the Lower Cretaceous Shahezi Formation in the Lishu Fault Sag of the Songliao Basin. By integrating multi-scale characterization techniques—including high-pressure mercury intrusion, N2/CO2 adsorption, and nuclear magnetic resonance (NMR)—we examined the pore networks across five identified lithofacies: organic-rich clayey shale, organic-rich mixed shale, organic-rich siliceous shale, organic clayey shale, and organic mixed shale. The results indicate that mesopores (2–50 nm) constitute the dominant fraction of pore volume (31.7%–56.6%), followed by micropores (10 μm). Notable lithofacies-dependent variations were observed: organic-rich clayey shale exhibits abundant organic pores, clay interlayer pores, and intragranular dissolution pores with favorable connectivity; organic-rich siliceous shale is mainly dominated by inorganic pores with limited organic porosity; mixed shales are characterized by clay mineral contraction fractures and intergranular pores. The key controlling factors are mineral composition and organic matter abundance: clay content shows a positive correlation with pore volume and surface area in organic-rich clayey shale, but a negative correlation in organic mixed shale. Brittle minerals (quartz and feldspar) generally reduce porosity through compaction. Total organic carbon (TOC) displays a weak positive correlation with mesopore volume, while thermal maturity (Ro = 1.2%–1.73%) exerts influences that vary by lithofacies. In contrast to marine shales—which are dominated by high-maturity (Ro > 2.0%) organic pores and quartz-supported frameworks—terrestrial shales primarily rely on inorganic pores derived from clay minerals (e.g., illite). This study clarifies the relationships among lithofacies, pore structure, and controlling factors, thereby providing a basis for evaluating the gas potential of terrestrial shales.
Bai et al. (Thu,) studied this question.