What question did this study set out to answer?

The aim is to efficiently oxidize glucose to formic acid using an ozone and polyoxometalate system.

February 2, 2026Open Access

Ozone-Oxidation of Glucose to Formic Acid over Polyoxmetalates

Key Points

The aim is to efficiently oxidize glucose to formic acid using an ozone and polyoxometalate system.
Developed a new oxidation approach with POM K10SiW9Mn3IIO37/O3 system
Conducted reactions at room temperature for 3 hours
Analyzed the influence of Mn-POM components on glucose conversion
Achieved 79.3% yield of formic acid
Demonstrated 82.1% conversion of glucose
Identified generation of reactive oxygen species as critical for formic acid production

Abstract

The efficient oxidation of glucose to formic acid (FA) has emerged as a sustainable method for biomass utilization. Herein, we developed a new approach to fulfill oxidation of glucose to formic acid using a polyoxometalate (POM) K10SiW9Mn3IIO37/O3 system, and its high efficiency was presented with 79.3% yield of FA at 82.1% conversion at room temperature for 3 h. As evidenced by experiments, the components in Mn-POMs significantly influenced glucose conversion due to their effect on generating reactive oxygen species (ROSs) from O3, which was essential for FA production.

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Cite This Study

Yu et al. (Thu,) studied this question.

synapsesocial.com/papers/6980fc91c1c9540dea80e6fa https://doi.org/https://doi.org/10.3390/molecules31030467

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