Remote α-and β-C(sp 3 )-H Alkenylation of Amines via Visible-Light Supported Paired Electrolysis

Key Points

• This research aims to develop a method for selective hydrogen activation and alkenylation of amines using visible light.
• Developed a method for photoelectrochemical C(sp 3 )-H alkenylation of amines
• Utilized vinyl bromides as reactants
• Achieved regioselective activation of C-H bonds
• Successfully demonstrated the alkenylation of both α- and β-positions in amines
• Showed effectiveness of the method under visible-light irradiation
• Indicated potential for broad application in organic synthesis