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Ru6(μ6-Sb)(CO)183-: Deeply Reduced Metal Carbonyl Cluster Embedded with Naked μ6-Sb | Synapse

February 6, 2026Dalton Transactions0 citations

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Ru6(μ6-Sb)(CO)183-: Deeply Reduced Metal Carbonyl Cluster Embedded with Naked μ6-Sb

CDCheng Ding XXXian Xu QQQian Qin

Key Points

This research aims to synthesize and characterize a new metal carbonyl cluster that includes a rare mu6-antimony unit.
Conducted a redox reaction between K3Sb and Ru3(CO)12.
Used ethylenediamine in the presence of 2,2,2-cryptand.
Characterized the resulting complex through standard analytical techniques.
Successfully synthesized [Ru6(μ6-Sb)(μ2-CO)2(CO)16]3- cluster.
Identified the unique boat-like structure of the Ru6 cluster unit.
Demonstrated the embedding of naked μ6-Sb in the metal carbonyl framework.

Abstract

The redox reaction of K3Sb and Ru3(CO)12 in the ethylenediamine (en) of 2,2,2-cryptand to produce the deeply reduced Ru6(μ6-Sb)(μ2-CO)2(CO)163- (1) wherein the unprecedented boat-like Ru6 cluster unit is embedded with...

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Cite This Study

Ding et al. (Thu,) studied this question.

synapsesocial.com/papers/698585758f7c464f23008e2d https://doi.org/https://doi.org/10.1039/d6dt00002a