One-pot asymmetric sulfoxidation using in situ generated H 2 O 2 from H 2 and O 2 catalyzed by rhodium and vanadium complexes

Key Points

• The research aims to explore a new method for asymmetric sulfoxidation using in situ generated hydrogen peroxide with specific catalysts.
• Utilized hydrogen and oxygen to generate hydrogen peroxide in situ.
• Employed rhodium and vanadium complexes as homogeneous catalysts.
• Conducted one-pot reactions for the sulfoxidation process.
• Successfully achieved asymmetric sulfoxidation in a single pot.
• Demonstrated the efficiency of using in situ generated hydrogen peroxide.
• Showed the potential of rhodium and vanadium complexes in catalyzing the reaction.