The research aims to explore how the functionalization of 6,6′-biazulene can facilitate electrochemical Hammett analysis.
Examined the electrochemical properties of 6,6′-biazulene
Performed Hammett analysis
Investigated long-range π-communication between molecular components
Identified key aspects of redox tunability in functionalized biazulenic structures
Demonstrated successful electrochemical analysis of Hammett constants
Abstract
Functionalization along the molecular axis of 6,6′-biazulene enables electrochemical Hammett analysis, precise redox tunability, and probing of long-range π-communication.