The coupling of physical transport and phase-transfer processes represents a fundamental mechanism governing metal cycling in estuarine systems under tidal oscillations. Taking Quanzhou Bay as a model system, we conducted continuous observations and sample collection at the river channel (Q1), the turbidity maximum zone (Q2), and the outer bay channel (Q3). The metals (Al, Ti, Ba, Cu, Mn, and Zn) were measured by ICP-MS to systematically investigate the distribution, transport, and inter-media transfer across multiple water layers under varying estuarine processes. Our findings demonstrate that particulate metal concentrations in Quanzhou Bay exhibit strong synchrony with suspended sediment concentrations (SSC) over tidal cycles, displaying a distinct sediment-following pattern controlled by alternating end members. Particulate metal fluxes during flood and ebb-tides generally followed the hierarchy Q1 > Q2 >> Q3. Notably, stations Q1 and Q2 were dominated by flood-tide fluxes with net transport directed landward, whereas Q3 was characterized by ebb tide dominance with net flux directed seaward—revealing a spatial division of labor between “inner bay retention/reallocation” and “outer bay channel export”. In contrast, dissolved metals exhibited marked element-specific responses to tidal forcing: Al and Ti increased during flood tides at stations Q1 and Q2, while Ba and Cu showed opposite trends, and Mn and Zn displayed more conservative behavior. Concurrently, solid/liquid partition coefficient (logKd) values for Al, Ti and Ba, Cu exhibited inverse patterns over tidal cycles, suggesting divergent adsorption–desorption regulation under identical hydrodynamic conditions that drives differential phase-transfer dynamics. These disparities likely reflect intrinsic chemical properties and source variations among the elements. This study elucidates, at the tidal timescale, the coupled processes of “alternating end-member control—estuarine filter modulation—concurrent channelized export and inner bay retention” in Quanzhou Bay, providing critical process-level insights for metal flux quantification and bay pollution remediation initiatives in an ecological restoration project.
Fan et al. (Sat,) studied this question.