The reaction of the anionic complex 1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10–X+ (X = Na, PPN+, tmndH+) with THF in the presence of initiators (BF3·Et2O, H2SO4, AlCl3) leads to the formation of the neutral complex 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9 with a THF molecule at the boron atom in the B6 position of the carborane ligand. Structure of the complex was established by multinuclear NMR, IR spectroscopy, and elemental analysis methods.
Balagurova et al. (Tue,) studied this question.
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