Coordination Compounds of Silver(i) Nitrate With Several Amide Ligands: Synthesis, Structure, Properties

Key Points

• The central aim is to investigate the formation and properties of coordination compounds of silver(I) with various amide ligands.
• Synthesis of silver(I) coordination compounds in aqueous solution.
• Structural characterization of the compounds using DFT and QTAIM methods.
• Assessment of bond strength between silver and ligands.
• Thermal analysis through TGA to study thermal properties.
• Three new coordination polymers were isolated and characterized.
• Silver coordination environments were detailed using theoretical methods.
• Bond strengths between Ag(I) and amide/nitrate ligands were estimated.
• Thermal degradation mechanisms were suggested based on TGA data.