Carbon-fiber-reinforced polymer (CFRP) composites possess outstanding specific stiffness and strength but typically exhibit low intrinsic damping, which limits vibration attenuation in lightweight dynamic structures. Herein, a hybrid toughening strategy combining carboxyl-terminated butadiene nitrile rubber (CTBN) and hexagonal boron nitride (h-BN) is developed to enhance the damping of CFRP laminates while preserving cure feasibility and thermomechanical stability. An E51/DICY/accelerator epoxy system (100: 6. 5: 1. 2, mass ratio) is used as the baseline matrix. Differential scanning calorimetry shows that both CTBN and h-BN shift the cure peak temperature upward (Tp: 160. 6 → 170. 3 °C) and reduce the reaction enthalpy (ΔH: 386. 5 → 255. 1 J/g), indicating dilution/transport effects and altered cure kinetics. Dynamic mechanical analysis (DMA) reveals that CTBN exhibits an optimum damping enhancement at 25 phr (tan δₘax = 0. 300), whereas h-BN provides a stronger monotonic increase up to 25 phr (tan δₘax = 0. 437). Notably, the CTBN/h-BN hybrid (25/25 phr) delivers a high tan δₘax of 0. 468 together with the broadest effective damping window (ΔTₕalf = 28. 6 °C), exceeding 85% of the linear additivity criterion proposed herein. When the materials are transferred into CFRP laminates, free-vibration tests (using the logarithmic decrement method) demonstrate a clear structural damping improvement (ζ: 0. 021 → 0. 035; δ: 0. 132 → 0. 221; t1/2: 0. 48 → 0. 27 s). Overall, the results suggest that the damping enhancement arises from a combination of EPBN-mediated ductile energy dissipation and h-BN-related interfacial/interlayer frictional losses, which can be jointly tuned to balance processability, thermal response, and damping performance in CFRPs.
Wang et al. (Fri,) studied this question.