Selenium (Se) is an essential trace element for humans, and agricultural soils are a major source of dietary Se. Therefore, identifying the key environmental drivers of Se in farmland is crucial for evaluating the resource base for Se-rich agriculture and improving human health. Although soil Se distribution and its controlling factors have been widely investigated, quantitative assessments of soil Se in small-scale farmland systems under humid monsoon conditions remain limited. Sampling sites were designed to represent different geological types, soil types, and topography, and 314 farmland topsoil (0–20 cm) samples were collected. Total Se was determined after complete HNO3–HClO4 wet digestion and quantified by HG–AFS (AFS–830), with certified reference materials showing recoveries of 95.3–101.2%. The spatial patterns were mapped using ordinary kriging. Geographically weighted regression (GWR) and Geodetector were used to explore the impact of environmental factors (geological type, precipitation, etc.) on soil Se from both local and overall perspectives. The findings reveal a mean total soil Se of 1.76 mg/kg (95% CI: 1.540–1.974), and 91.40% (n = 287) of soil samples were classified as Se-rich (0.4–3 mg/kg). Organic matter (OM), elevation, slope, and the topographic wetness index (TWI) exhibited non-stationary spatial relationships with Se. The spatial variation trend of precipitation corresponds with the local R2 values between Se and elevation, indicating that precipitation may strengthen the association between elevation and Se distribution. Geological type and rainfall were identified as key driving factors affecting soil Se content within the study area, particularly through their interactions with OM. Overall, the synergistic effects of geological type, precipitation, and OM are responsible for the accumulation of Se in the agricultural soils of Xin’an Town.
Guo et al. (Fri,) studied this question.