Mining tailings are waste generated continuously in large quantities and have accumulated over time, posing significant environmental challenges. This study evaluates the influence of low (MinPC) and high (MaxPC) current densities on the recovery of elements from untreated mining tailings obtained from SCM Paicaví by electrodeposition. To define both conditions, tailings were placed in containers with electrodes spaced 3–18 cm apart, and controlled currents of 1–100 mA were applied. Although MaxPC electrodes recovered a greater mass of material (1.51 g) than MinPC (0.22 g), the latter achieved higher enrichment of elements such as Ni and Mn. Under MinPC conditions, Ni exhibited the highest recovery, enrichment (19.3), and selectivity (4.8), whereas under MaxPC, the enrichment and selectivity decreased to 9.6 and 2.0, respectively. Elemental analyses (XRF, AAS, ICP-MS), together with mineralogical characterization (XRD, FT-IR, and SEM-EDS), identified quartz, pyrite, and chlorite as the main phases associated with the recovered elements. Overall, the results demonstrate that direct electrodeposition enables selective metal recovery from untreated tailings without pretreatment, chemical reagents, or additional water consumption, providing a novel and environmentally sustainable route for tailings valorization.
Aburto-Hole et al. (Sun,) studied this question.