High-performance birefringent crystals are crucial for advancing modern optics. Regrettably, conventional birefringent crystals are usually limited by narrow transmission windows or insufficient birefringence. Recognizing that birefringence originates from structural anisotropy, we herein assembled anisotropic π-conjugated urea ligands through a cadmium-based open framework. By leveraging the distorted Cd-based octahedra and urea-derived hydrogen-bonding network, a novel birefringent crystal, CdC (NH2) 2O2Cl2, was successfully obtained. CdC (NH2) 2O2Cl2 was characterized by a characteristic 4 × 4 × 6 open-framework skeleton, wherein the repeating building unit CdC (NH2) 2O2Cl4 is constructed by the oxygen sharing between distorted CdCl4O2 octahedra and planar C (NH2) 2O groups. Notably, CdC (NH2) 2O2Cl2 achieved an excellent balance between wide bandgap and substantial optical anisotropy by exhibiting a short UV cutoff edge of 201 nm and a birefringence of 0. 117@546 nm, which should benefit practical applications.
Ma et al. (Tue,) studied this question.