Conventional hydrochloric acid (HCl) acidizing in carbonate reservoirs is often limited by excessively rapid acid–rock reactions and preferential flow through high-permeability paths, resulting in shallow penetration and inefficient stimulation. Viscoelastic surfactant (VES)-based diverting acids have been widely applied to address these challenges; however, the intrinsic relationship between reaction retardation and diversion efficiency, particularly under varying shear conditions, remains insufficiently clarified. In this study, a VES-based diverting acid system formulated with erucamidopropyl hydroxysultaine (EH50) was systematically investigated through multiscale experiments, including rotating disk reaction kinetics, rheological characterization, porous core flooding, and fracture-scale plate flow tests. The results reveal a pronounced shear-dependent transition in the governing mechanism of the system. Under low-shear conditions, the VES system significantly reduces the apparent acid–rock reaction rate, with a maximum reduction of 77.3%, and exhibits a synergistic retardation effect in the presence of Ca2+, indicating mass transfer limitation. However, under high-shear porous media flow, the intrinsic retarding effect is substantially weakened due to partial disruption of the viscoelastic structure. Despite this attenuation of chemical retardation, effective diversion performance persists under dynamic flow conditions, manifested by pressure plateau behavior, enhanced flow redistribution, more distributed wormhole networks, and greater overall dissolution. Fracture-scale experiments further demonstrate that the diversion acid suppresses excessive inlet etching and promotes spatially distributed etching patterns favorable for fracture conductivity maintenance. These findings clarify that reaction retardation and diversion are distinct yet dynamically coupled mechanisms, whose relative dominance depends on shear intensity and ionic environment. The proposed shear-responsive mechanism framework provides new insight into the design and optimization of VES diverting acid systems for carbonate reservoir stimulation.
Tian et al. (Mon,) studied this question.