The reverse water–gas shift reaction represents a crucial route for CO2 utilization, yet developing catalysts that combine high activity, selectivity, and long-term stability at high temperatures remains a great challenge. This work presents a robust and highly selective catalyst system constructed by supporting nanosized oxides CeO2 on a bulk InNi3C0.5 carbide. The optimal 30CeO2/InNi3C0.5 catalyst achieves a CO formation rate of 7358 μmolCO·gcat–1·s–1 at 600 °C under an ultrahigh weight hourly space velocity of 12,000 L·gcat–1·h–1, surpassing most reported catalysts. More importantly, it exhibits robust stability for over 100 h at 600 °C, with minimal deactivation. A combination of mechanistic investigations reveals that the CeO2–InNi3C0.5 interface not only enhances CO2 adsorption and suppresses the sintering of the carbide phase but also introduces an associative formate-mediated pathway that operates in parallel with the classical redox pathway on the carbide. This dual-pathway mechanism accounts for the enhanced kinetics. Furthermore, the other metal oxides, such as Y2O3 and MgO, offer similar promotional effects, which confirms the generality of the “oxide-carbide interface” strategy and provides a versatile paradigm for designing advanced thermocatalysts for CO2 conversion.
Gao et al. (Fri,) studied this question.