What question did this study set out to answer?

Investigate the adaptive metal binding properties of a diphosphine-based zirconium metal-organic cage.

April 1, 2026Dalton Transactions0 citations

In or out? Adaptive metal binding by a diphosphine-based Zr metal-organic cage

Key Points

Investigate the adaptive metal binding properties of a diphosphine-based zirconium metal-organic cage.
Synthesis of a lantern-type zirconium metal-organic cage using ditopic carboxylate linkers
Characterization using single-crystal X-ray diffraction
Successful synthesis of the metal-organic cage Zr-P2N2
Demonstration of adaptive metal binding through diphosphine groups

Abstract

A lantern-type Zr metal-organic cage (MOC), Zr-P 2 N 2 , has been synthesized using ditopic carboxylate linkers based on the 1,5-diaza-3,7-diphosphacyclooctane (P 2 N 2 ) ligand platform. Single-crystal X-ray diffraction shows that the diphosphine groups of...

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Cite This Study

Shin et al. (Thu,) studied this question.

synapsesocial.com/papers/69cd7b575652765b073a94e4 https://doi.org/https://doi.org/10.1039/d6dt00536e

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