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April 3, 2026Chemical Science0 citationsOpen Access

Alkali Metal Cation Effects for Rapid C–H Activation by Iron(0) Complexes

NHNereida Hidalgo KSKendal Southwell RDRyan Donnelly

Key Points

To investigate how alkali metal cations affect the C–H activation rate in iron(0) complexes.
Utilized diketiminate-supported iron(0) complexes
Applied ion pairing with various alkali metal cations
Measured activation rates of C–H bonds
Demonstrated increased rates of C–H activation with specific alkali metal cations
Observed optimal ion pairing conditions for enhanced activity
Identified that unique interactions between cations and iron(0) complexes facilitate activation

Abstract

Ion pairing with alkali metal cations offers a novel way to enhance the rate of C–H activation. This strategy is demonstrated here using diketiminate-supported iron(0) complexes, which previously were shown...

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Alkali Metal Cation Effects for Rapid C–H Activation by Iron(0) Complexes | Synapse

Cite This Study

Hidalgo et al. (Thu,) studied this question.

synapsesocial.com/papers/69cf5de95a333a821460bf40 https://doi.org/https://doi.org/10.1039/d6sc01470d