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Role of M-site cation in The Negative Linear Compressibility of Rutile-Like M II (dca) 2 | Synapse

April 19, 2026Inorganic Chemistry Frontiers0 citationsOpen Access

Role of M-site cation in The Negative Linear Compressibility of Rutile-Like M II (dca) 2

MCMuzi Chen HBHanna Boström DDDominik Daisenberger

Key Points

This research aims to understand how different M-site cations affect the structural behavior of rutile-like materials under pressure.
Utilized synchrotron high-pressure powder X-ray diffraction
Analyzed structural changes in rutile-like network materials with M = Mn, Fe, Ni
Conducted experiments at varying pressure conditions
Observed negative linear compressibility in certain materials
Identified distinct pressure-induced structural deformations related to M-site cations
Noted variations in behavior among different metal cations (Mn, Fe, Ni)

Abstract

We investigate the pressure-induced structural deformations in a series of rutile-like network materials, M(dca) 2 (M = Mn, Fe, Ni), using synchrotron high-pressure powder X-ray diffraction (HP-PXRD). These materials adopt an...

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Cite This Study

Chen et al. (Thu,) studied this question.

synapsesocial.com/papers/69e4741c010ef96374d8fd0b https://doi.org/https://doi.org/10.1039/d6qi00392c