Polycrystalline La2−xBixNiMnO6 (x = 0.2, 0.5, 1.0) samples were synthesized via a high-temperature and high-pressure method, with their structural, magnetic, and electrical properties systematically characterized. X-ray diffraction (XRD) confirms a monoclinic double perovskite structure (space group P21/n) for all samples, while Bi3+ induces a lattice volume expansion trend inferred from XRD peak shifts due to its larger ionic radius than La3+. Magnetically, all exhibit ferromagnetism and soft magnetic features, with magnetization decreasing as Bi content increases. The x = 0.2 and 0.5 samples show two distinct Curie temperatures, both decreasing with Bi substitution, whereas the higher Curie temperature vanishes in the x = 1.0 sample, likely due to Bi-induced structural changes. Electrically, all display semiconducting behavior (resistivity: x = 0.5 > x = 0.2 > x = 1.0) and negative magnetoresistance (MR) at 200 K, peaking at 12% (x = 0.5) and 7.5% (x = 1.0). For the x = 1.0 sample, negative magnetoresistance strengthens with decreasing temperature (130–200 K), with magnetoresistance-field (MR-H) curves showing herringbone and arc shapes.
Lei Xing (Fri,) studied this question.