Symmetry-Directed Complex Tessellation of Irregular Polygons from a Single Molecular Precursor

Key Points

• The main aim is to overcome challenges in constructing two-dimensional tessellations using irregular polygons in supramolecular chemistry.
• Utilized a single molecular precursor to construct tessellations
• Applied symmetry-directed techniques for ordering
• Analyzed the geometric properties of the resultant structures.
• Successfully achieved periodic ordering of irregular polygons
• Demonstrated significant improvements in tessellation complexity
• Highlighted the role of geometric regularity in design outcomes.