During service in engineering fields, the performance of carbon black (CB)/silica-filled rubber suffers degradation because of the influence of aging. In the process of reproducing the mechanical behavior of CB/silica-filled rubber, many constitutive models have been proposed. However, the model selection strategy taking the aging effect into consideration is still unclear, especially the classical model selection strategy. In this work, the effects of thermo-oxidative and ultraviolet aging on the nonlinear viscoelasticity of CB/silica -filled rubber were investigated using dynamic mechanical analysis tests. It was found that aging conditions had a great effect on the nonlinear viscoelasticity of CB/silica -filled rubber. Meanwhile, the degradation mechanisms were discussed on the basis of the existing works. To accurately reproduce the nonlinear viscoelasticity degradation, classical models, such as the Kraus model and Maier–Göritz model, were used to describe the experimental data. In the reproducing process, fitting correlation coefficients and root mean square error were used to verify the reliability of classical models. Comparingsimulation results and experimental ones, it was found that the Maier–Göritz model was more reliable under all aging conditions. This work will contribute to a model selection strategy and a deeper understanding of the degradation mechanism.
Li et al. (Fri,) studied this question.
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