A Practical Guide to RRKM Theory, its Simplified Multi-Well Version AWATAR and Master Equation Modelling of Radiative Processes

Key Points

• The aim is to present a practical understanding of RRKM theory, its simplified multi-well version AWATAR, and the modelling of radiative processes.
• Details on applying RRKM theory and AWATAR in gas phase reactions
• Insights on modelling radiative processes using the master equation
• Discussion on the limitations of equilibrium thermodynamics in ultra-high vacuum conditions
• Improved understanding of unimolecular reaction behaviour in the absence of traditional heat baths
• Highlighting the role of radiative thermalization in reaction kinetics
• Establishment of AWATAR as a useful tool in modelling