Silicomanganese slag (SiMnS), a Mn-bearing by-product from silicomanganese alloy production, is often stockpiled in large quantities and may pose environmental concerns due to potential metal leaching. This study develops an OPC-rich hybrid SiMnS–steel slag–fly ash–OPC-activated composite binder, referred to as SMSAB, in which OPC accounts for 55% of the solid precursor mass. Different alkali contents and sodium silicate moduli were investigated, and the optimised paste was characterised in terms of mechanical strength, reaction products, pore structure, carbon-footprint and heavy-metal leaching. The best performance was obtained at an alkali content of 4% and a sodium silicate modulus of 1.0, giving 28-day compressive and flexural strengths of 65.13 MPa and 3.37 MPa, respectively. XRD, SEM-EDS, FTIR and MIP results showed that the main reaction products were C-(A)-S-H, N-A-S-H and C-N-A-S-H gels, which refined the pore structure and produced a dense matrix. The reduction in Mn leaching may be associated with physical encapsulation, possible charge-balancing interactions within gel structures, changes in Mn-related bonding environments and the presence of Mn-bearing phases. Leaching concentrations of Zn, Mn, Cr, Cu and Ni satisfied the Grade III groundwater limits used in China. The calculated carbon intensity of SMSAB was 3.97 kg·(m3·MPa)−1, indicating a favourable strength-to-emission balance compared with the reference systems considered. It should be noted that the present work examines paste specimens only; aggregate skeleton, traffic loading, freeze–thaw cycling and wet–dry/moisture cycling were not included. Therefore, the results demonstrate binder-level potential rather than direct qualification of SMSAB as a pavement base or subbase material.
Duan et al. (Mon,) studied this question.