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Stereospecific SuFEx Reactivity of Highly Enantioenriched Sulfondiimidoyl Fluorides | Synapse

May 8, 2026Open Access

Stereospecific SuFEx Reactivity of Highly Enantioenriched Sulfondiimidoyl Fluorides

Key Points

The study aims to explore the stereospecific reactivity of sulfondiimidoyl fluorides in asymmetric synthesis.
Investigated the SuFEx transformations of enantioenriched sulfondiimidoyl fluorides.
Utilized various reaction conditions to optimize stereospecific outcomes.
Successful transformation of enantioenriched sulfondiimidoyl fluorides into sulfone diimines with high stereospecificity.
Greater yields observed from specific reaction configurations.

Abstract

Sulfondiimidoyl fluorides are established SuFEx platforms, yet their potential in asymmetric synthesis remains largely unexplored. Herein we report stereospecific SuFEx transformations of highly enantioenriched sulfondiimidoyl fluorides to access sulfone diimines,...

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Authors

G

Glebs Jersovs

A

Aldis J Pivars

J

Julija Bariseva

Journals

Organic Chemistry Frontiers

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Cite this study

Jersovs et al. (Thu,) studied this question.

www.synapsesocial.com/papers/69fd7fb8bfa21ec5bbf083ca — DOI: https://doi.org/10.1039/d6qo00230g