This research aims to synthesize metallopolymers using thermal dealkylation of bisphosphanylferrocene precursors.
Employ thermal ring expansion polymerization to prepare ferrocenylene-bridged polyphosphanes.
Characterize resulting metallopolymers using various analytical methods.
Successfully synthesized ferrocenylene-bridged polyphosphanes with unique properties.
Demonstrated significant potential for applications in advanced materials.
Abstract
Ferrocenylene-bridged polyphosphanes Fc'P 2 n t Bu 2 and Fc'P 2 n (Fc' = 1,1'-ferrocenediyl; t Bu = tert-butyl, previously prepared via thermal ring expansion polymerization from strained...