Chirality dominance in seeded supramolecular copolymerization of complementary perylenediimides

Key Points

• This research aims to investigate the chirality and copolymerization behavior of BQQDI in supramolecular systems.
• Synthesis of chiral 3,4,9,10-benzo[d,e]isoquinolino [1,8g,h]quinolinetetracarboxylic diimide (BQQDI)
• Evaluation of self-assembly behavior in the presence of electron-withdrawing pyridine rings
• Assessment of copolymerization efficiency with complementary perylenediimides.
• Self-assembly occurs effectively due to the chiral nature of BQQDI.
• Pyridine rings enhance the copolymerization process, promoting stronger intermolecular interactions.