Catalytic Aerobic Sulfonyloximation of Alkenes Enabled by the Nitric Oxide-Donor Role of 2-Nitropropane

Key Points

• The aim is to explore the catalytic aerobic sulfonyloximation of alkenes using 2-nitropropane as a nitric oxide donor.
• Utilized 2-nitropropane to donate nitric oxide during reactions.
• Employed mild conditions for the synthesis process.
• Generated a variety of structurally diverse β-sulfonyl oximes.
• Achieved a broad substrate scope with successful formation of β-sulfonyl oximes.
• Demonstrated potential for nitrous oxide incorporation in radical reactions.