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本综述总结了催化不对称脱芳构(CADA)反应的发展。本文讨论的CADA反应包括氧化脱芳构反应、通过Diels-Alder及相关反应的脱芳构、富电子芳烃的烷基化脱芳构、过渡金属催化的脱芳构反应、以不对称脱芳构为关键步骤的级联序列,以及吡啶鎓衍生物的亲核脱芳构反应。文中还简要介绍了含手性助剂的不对称脱芳构反应以及脱芳构底物的催化不对称反应。该综述旨在为催化不对称脱芳构提供一个概念。
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Chun‐Xiang Zhuo
Wei Zhang
Shu‐Li You
Angewandte Chemie International Edition
Chinese Academy of Sciences
Shanghai Institute of Organic Chemistry
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Zhuo等人(Mon,)研究了这个问题。
www.synapsesocial.com/papers/69d6b9cf75cae9790bed897d — DOI: https://doi.org/10.1002/anie.201204822
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