January 1, 2022Open Access

杂环芳烃脱芳香化功能化的最新进展

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Abstract

（杂）芳烃的脱芳香化反应作为获得高取代饱和环化合物的有效方法，已被广泛应用超过一个世纪。近年来，该领域的研究重点转向在整体脱芳香化过程中实现额外的C-C键形成。不同于传统的氢化策略，发现多种试剂能够通过亲核加成（通常是还原反应）或光化学诱导的自由基加成来启动脱芳香化。脱芳香化过程中产生的活性中间体可以通过分子内或分子间的方式被截留，从而生成分子复杂度显著高于单纯脱芳香化的产物。在本观点文章中，将讨论杂芳环系统脱芳香化功能化的最新实例和策略。

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Authors

Nicolas Kratena

Bruno Marinič

Timothy J. Donohoe

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Chemical Science

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University of Oxford

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杂环芳烃脱芳香化功能化的最新进展

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