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May 6, 2026Angewandte Chemie

Pre‐Activated Cascade Redox Enables High‐Voltage Multi‐Electron Anion Storage in Graphite

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Authors

ZSZhiqin SunHJHonglei JiangPLPi Liu

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Overview

This approach demonstrates enhanced anion storage capacity in graphite, indicating improved energy storage performance with multi-electron redox pathways.

Key Points

  • The research aims to enhance anion storage in graphite cathodes for dual-ion batteries by enabling multi-electron redox chemistry.
  • Developed iron‐chloride‐intercalated graphite
  • Studied the pre‐activated, cascade multi‐electron redox pathway
  • Evaluated oxidation processes of iron and chlorine
  • Measured performance metrics under various conditions.
  • Achieved an average transfer of 2.61 electrons per redox event
  • Delivered a stable capacity of 52 mAh g −1 at 3 A g −1
  • Outperformed conventional graphite cathodes with only 15 mAh g −1
  • Enabled operation up to 5 V (vs. Na/Na + ).

Cite This Study

Sun et al. (2026) studied this question.

synapsesocial.com/papers/69fa989404f884e66b5324d2https://doi.org/10.1002/ange.5529195
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