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April 25, 2026The Journal of Chemical Physics0 citationsOpen Access

Expansion of time-convolutionless non-Markovian quantum master equations: A case study using the Fano–Anderson model

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TATim AlhäuserHBHeinz‐Peter Breuer

Key Points

  • The study aims to evaluate the TCL projection operator technique in the context of the Fano-Anderson model.
  • Utilized the Fano-Anderson model to compare exact TCL master equations with expansions based on system-environment coupling.
  • Analyzed transient dynamics and steady-state behavior with Lorentzian spectral density.
  • Examined quantum non-Markovianity through the evolution of Bures distance between quantum states.
  • The TCL expansion's convergence radius varies with the detuning and width of the spectral density.
  • The Bures distance revealed significant aspects of quantum non-Markovianity, showing dependence on the expansion’s second and fourth orders.
  • The study indicates challenges in effectively describing strongly coupled systems and non-Markovian dynamics.

Abstract

We explore the performance of the time-convolutionless (TCL) projection operator technique using the Fano-Anderson model as a test case. Comparing the exact TCL master equation with an expansion in powers of the strength of the system-environment coupling, we analyze the transient dynamics as well as the steady-state behavior. For a Lorentzian spectral density, we demonstrate that the dimensionless expansion parameter corresponds to the ratio of the environmental correlation time to the relaxation time of the system, and we derive the convergence radius for the TCL expansion, which is seen to depend on the ratio of detuning and width of the spectral density. We further study the quantum non-Markovianity of the model based on the evolution of the Bures distance between quantum states and how it is represented by the second and fourth orders of the expansion. Our results highlight both the strengths and the limitations of the TCL formalism in capturing key features of open quantum systems and, in particular, the challenges of accurately describing strongly coupled systems and non-Markovian dynamics.

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Cite This Study

Alhäuser et al. (2026) studied this question.

synapsesocial.com/papers/69ec5bd288ba6daa22dad2f6https://doi.org/10.1063/5.0323348
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