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Synapse
May 8, 2026Green Chemistry0 citationsOpen Access

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Key Points

  • The research aims to convert poly(-caprolactone) into azepane using a titanium oxide-supported platinum catalyst.
  • Direct conversion of poly(-caprolactone) into azepane via reductive ammonolysis
  • Utilization of a reusable Pt/TiO2 catalyst
  • Investigation of catalytic performance based on the synergistic roles of TiO2 and Pt
  • High catalytic performance observed with the Pt/TiO2 catalyst
  • TiO2 facilitates depolymerization while Pt nanoparticles activate H2
  • Effective conversion leads to azepane formation with sustainable catalyst utilization

Abstract

Upcycling poly(-caprolactone) into azepane via reductive ammonolysis over a titanium oxide-supported platinum catalystThis work highlights the direct conversion of poly (-caprolactone) into azepane, a seven-membered N-heterocycle, using a reusable Pt/TiO 2 catalyst.The high catalytic performance is attributed to the synergistic roles of TiO 2 and Pt nanoparticles: TiO 2 promotes depolymerization, while Pt nanoparticles activate H 2 .

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Cite This Study

A 2026 study studied this question.

synapsesocial.com/papers/69fd7d4abfa21ec5bbf05e11https://doi.org/10.1039/d6gc90090a
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