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April 12, 2026Nature CommunicationsOpen Access

Structural motifs of gold cluster anions with 17 to 69 atoms

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Authors

AAAndrés AguadoPÁPablo Álvarez-ZapateroOKOleg Kostko

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Overview

Identifies geometries of gold cluster anions, demonstrating their unique structures and bonding properties.

Key Points

  • The research aims to identify the structural motifs of gold cluster anions with 17 to 69 atoms.
  • Optimized DFT calculations were used to compare simulated and measured photoelectron spectra.
  • Extensive structural searches were conducted to explore different geometries of gold clusters.
  • Spectral data from simulations were matched with experimental results for validation.
  • DFT calculations achieved close to perfect agreement with measured photoelectron spectra.
  • Many identified gold cluster anions exhibited highly symmetric geometries.
  • The findings suggest gold’s bonding properties favor regular structures over amorphous ones.

Cite This Study

Aguado et al. (2026) studied this question.

synapsesocial.com/papers/69db38534fe01fead37c69adhttps://doi.org/10.1038/s41467-026-71649-9
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