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April 21, 2026Химия в интересах устойчивого развития0 citations

An Efficient Approach to Obtain Trityl Radicals That Are Highly Stable to the Presence of Superoxide

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ORO.YU. ROGOZHNIKOVAДТД.В. ТРУХИНАРА.Е. РАЙЗВИХ

Key Points

  • The study aims to develop triarylmethyl radicals with enhanced stability against superoxide by modifying the trityl core.
  • Modified the Finland-type trityl core by replacing carboxyl groups with alkoxymethyl substituents.
  • Synthesize new trityl radicals and assess their stability in superoxide environments.
  • The newly created triarylmethyl radicals displayed extremely high stability when exposed to superoxide.
  • This structural modification led to improved resistance compared to traditional trityl radicals.

Abstract

Structural modification of the Finland-type trityl core by replacing carboxyl groups by alkoxymethyl substituents (CH2OCH2CO2H) resulted in new triarylmethyl radicals, which showed extremely high stability in the presence of superoxide.

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Cite This Study

ROGOZHNIKOVA et al. (2025) studied this question.

synapsesocial.com/papers/69e713decb99343efc98d4a2https://doi.org/10.15372/csd2025691
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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1ANALYSIS OF THE OXIDATIVE DESTRUCTION ROUTES OF TRITYL RADICALS CAUSED BY SUPEROXIDE2025
  2. 2Hydroxymethyl‐Substituted Tetrathiatriarylmethanol with Variable Reactivity: Selective Access to Three Different Trityl Radicals by Unique Acid‐Mediated Reactions2024 · 1 citations
  3. 3Diversifying Trityl Radicals via Oxidative Radical-Polar Crossover in Tandem with Aromatic Nucleophilic Substitution2026
  4. 4An Air-Stable Carbon-Centered Triradical with a Well-Addressable Quartet Ground State2024 · 33 citations
  5. 5Stable Diphenylamine‐Substituted Tris(2,4,6‐trichlorophenyl)methyl Radical Oligomers: Synthesis, Optical Properties, and Redox Chemistry2025 · 1 citations