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May 21, 2026BHM Berg- und Hüttenmännische Monatshefte0 citationsOpen Access

Effects of Mn/S Ratios and Cooling Conditions on High-temperature Embrittlement in Continuous Casting

TTTakuya TakayamaGGGeorg GaiserRLRobert Littringer

Key Points

  • The study aims to explore how Mn/S ratios and cooling conditions affect embrittlement during continuous casting.
  • Used In-Situ Material Characterization by Bending (IMC-B) test for evaluation.
  • Investigated different Mn/S ratios and cooling conditions during continuous casting.
  • Analyzed fracture surfaces using FE-SEM to identify precipitate effects.
  • At low Mn/S ratios and rapid cooling, significant surface cracks occurred.
  • Fine (Mn, Fe) S precipitates along austenite grain boundaries contributed to embrittlement.
  • Mild cooling reduced crack susceptibility by promoting sulfide growth and altering density.

Abstract

Abstract The demand for high-quality steel products has been increasing in recent years. During continuous casting of those steels, the prevention of defect formation is crucial to ensure the highest surface quality. This contribution focuses on the effects of different Mn/S ratios and cooling conditions on the high-temperature embrittlement under continuous casting conditions using the In-Situ Material Characterization by Bending (IMC-B) test. At low Mn/S ratio and rapid cooling conditions, large surface cracks were observed. A FE-SEM investigation of the fracture surface revealed that fine (Mn, Fe) S precipitated along prior austenite grain boundaries may be considered to be the primary factor of embrittlement. Mild cooling promoted sulfide growth and reduced the number density, thereby decreasing crack susceptibility. Contrary to hot tensile tests, embrittlement was observed even at low strain rates. This discrepancy is attributed to differences in the amount of applied strain associated with the evaluation methods. Results from the present study indicate the importance of understanding the characteristics of evaluation methods and their differences from actual processes.

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Cite This Study

Takayama et al. (2026) studied this question.

synapsesocial.com/papers/6a0ea17cbe05d6e3efb6030ehttps://doi.org/10.1007/s00501-026-01742-5
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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1The Interaction Between Oxidation-Related Phenomena Along Grain Boundaries on Surface Crack Formation in Continuous Casting2025 · 6 citations
  2. 2Some considerations of strength and ductility in the continuous-casting process1972 · 159 citations
  3. 3Modeling of manganese sulfide formation during the solidification of steel2016 · 65 citations
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  5. 5Critical evaluations and thermodynamic optimizations of the Mn–S and the Fe–Mn–S systems2010 · 16 citations