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April 30, 2007Angewandte Chemie International Edition1,636 citations

From Glycerol to Value‐Added Products

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MPMario PagliaroRCRosaria CiriminnaHKHiroshi Kimura

Key Points

  • To review technological advances and selective processes that convert surplus glycerol from biodiesel production into commercially valuable chemical derivatives.
  • Synthesized recent industrial and academic literature regarding the market shift caused by surplus glycerol generated from biodiesel manufacturing.
  • Evaluated selective chemical transformation pathways and catalytic processes used to upgrade crude glycerol into high-value functional compounds.
  • Identified multiple selective conversion processes capable of transforming low-cost glycerol into high-demand chemical derivatives.
  • Demonstrated the industrial shift from dedicated glycerol synthesis toward utilizing biodiesel byproducts as a central chemical feedstock.

Abstract

Today, industrial plants that produce glycerol are closing down and others are opening that use glycerol as a raw material, owing to the large surplus of glycerol formed as a by-product during the production of biodiesel. Research efforts to find new applications of glycerol as a low-cost feedstock for functional derivatives have led to the introduction of a number of selective processes for converting glycerol into commercially valued products. This Minireview describes a selection of such achievements and shows how glycerol will be a central raw material in future chemical industries.

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Cite This Study

Pagliaro et al. (2007) studied this question.

synapsesocial.com/papers/69d70ee975cae9790bed91e5https://doi.org/10.1002/anie.200604694
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