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May 7, 20263 citations

Amino-functionalized chitosan/carboxymethyl cellulose aerogel for efficient Cr(VI) removal and its carbonized derivative as a photocatalyst for tetracycline degradation.

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LHLixin HuangYTYongjie TuoJWJunqi Wei

Key Points

  • This research aims to develop a chitosan/carboxymethyl cellulose aerogel for Cr(VI) removal and its carbonized derivative for tetracycline degradation.
  • Preparation of amino-functionalized chitosan/carboxymethyl cellulose aerogel
  • Characterization of photocatalytic activity under visible light
  • Application of density functional theory for degradation pathway analysis
  • Liquid chromatography-mass spectrometry analysis of degradation products
  • Achieved 97.8% tetracycline degradation within 60 minutes
  • Identified degradation pathways including hydroxylation, demethylation, amide cleavage, and ring opening
  • Proposed an integrated adsorption-conversion-catalysis strategy for pollution control

Abstract

@CN photocatalyst, which degraded 97.8% of tetracycline within 60 min under visible light. The degradation pathways, elucidated through density functional theory (DFT) calculations and liquid chromatography-mass spectrometry (LC-MS) analysis, were found to involve hydroxylation, demethylation, amide cleavage, and ring opening, ultimately leading to mineralization. This work presents an integrated adsorption-conversion-catalysis strategy that enables the repurposing of hazardous heavy metal-laden waste into value-added photocatalytic materials, thereby providing a sustainable solution for synergistic pollution control and resource recovery.

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Cite This Study

Huang et al. (2026) studied this question.

synapsesocial.com/papers/69fbef68164b5133a91a33cdhttps://doi.org/10.1016/j.ijbiomac.2026.152355
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