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January 26, 2012Angewandte Chemie International Edition555 citations

Ultrathin W18O49 Nanowires with Diameters below 1 nm: Synthesis, Near‐Infrared Absorption, Photoluminescence, and Photochemical Reduction of Carbon Dioxide

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GXGuangcheng XiSOShuxin OuyangPLPeng Li

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Abstract

Open vacancies: A facile one-pot synthesis of oxygen-vacancy-rich ultrathin W18O49 nanowires up to several micrometers long is described. In addition to unique optical properties, such as NIR absorption and blue-light emission, the nanowires show an unexpected ability to photochemically reduce carbon dioxide to methane (see picture) as a result of its defect structure caused by large quantities of oxygen vacancies.

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Cite This Study

Xi et al. (2012) studied this question.

synapsesocial.com/papers/6a0c6ef6e8a76b3043887b15https://doi.org/10.1002/anie.201107681
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