December 4, 2025Chemical Communications2 citations

Intriguing Metal-Ligand Interplays Leading to Diverse Al-H-M (M = Mg, Ca) Heterobimetallic Hydrides on a Picolyl-Based 3N Ligand

Key Points

Diverse hydrides were formed, indicating various outcomes linked to ligand variations.
Key findings reveal unique interactions between alkaline earth metals and the ligand.
Analysis of heterobimetallic compounds suggests crafted intermediates lead to divergent products.
Findings may inform future studies on metal-ligand dynamics in coordination chemistry.

Abstract

We report here heterobimetallic 'Al-H-M' (M = Mg, Ca) hydrides on a chemically non-innocent picolyl-derived ethylenediamine ligand. The two alkaline earths result similar Intermediates but ultimately diverge to different endings....

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Mandal et al. (2025) studied this question.

synapsesocial.com/papers/6930dc81ea1aef094cca2413 https://doi.org/10.1039/d5cc05693d

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December 4, 2025Chemical Communications2 citations

Intriguing Metal-Ligand Interplays Leading to Diverse Al-H-M (M = Mg, Ca) Heterobimetallic Hydrides on a Picolyl-Based 3N Ligand

View Full Paper

CMChhotan Mandal DMDebabrata Mukherjee

Key Points

Diverse hydrides were formed, indicating various outcomes linked to ligand variations.
Key findings reveal unique interactions between alkaline earth metals and the ligand.
Analysis of heterobimetallic compounds suggests crafted intermediates lead to divergent products.
Findings may inform future studies on metal-ligand dynamics in coordination chemistry.

Abstract

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Cite This Study

Mandal et al. (2025) studied this question.

synapsesocial.com/papers/6930dc81ea1aef094cca2413 https://doi.org/10.1039/d5cc05693d

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