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January 17, 2026The Journal of Chemical Physics

Janus MoXY (X/Y = S, Se, Te) monolayers for photocatalytic water splitting: Performance investigation and regulation via first-principles and nonadiabatic molecular dynamics

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Authors

HDHao DongYLYuna LiXHXin He

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Overview

Investigation reveals how elemental variation regulates photocatalytic performance in low-dimensional materials, indicating new material selection strategies.

Key Points

  • The aim is to investigate how elemental variation in MoXY monolayers affects their photocatalytic properties.
  • Employed first-principles calculations to analyze polarization effects
  • Conducted nonadiabatic molecular dynamics simulations to assess carrier dynamics
  • Examined band edge positions and reaction energy barriers
  • Considered the effects of temperature and electron–phonon coupling on carrier lifetime
  • Elemental variation significantly alters polarization, affecting photocatalytic performance
  • Lowered reaction energy barriers enhance water-splitting efficiency
  • Nonadiabatic coupling strength impacts excited-state carrier properties
  • Inclusion of temperature and electron–phonon coupling influences carrier lifetimes

Cite This Study

Dong et al. (2026) studied this question.

synapsesocial.com/papers/696b26d7d2a12237a934a0f1https://doi.org/10.1063/5.0307817
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