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January 17, 2026Chemical Science0 citationsOpen Access

Alumanyl Silanides as Multifunctional Reagents for Olefin Cycloaddition, CO Hydrosilylation, and Reductive CO Coupling

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MLMoritz LudwigJVJohannes VoiglandPVPetra Vasko

Key Points

  • Investigate the properties and potential applications of alumanyl silanides as reagents in various chemical reactions.
  • Implemented computational analysis to study alumanyl silanides' bonding characteristics.
  • Evaluated reactions involving olefin cycloaddition, CO hydrosilylation, and reductive CO coupling.
  • Identified the anionic Al-Si bond as a stabilizing factor in alumanyl silanides.
  • Demonstrated the presence of multiple-bond character in the alumanyl silanides.
  • Showed promising efficiency of alumanyl silanides in key chemical transformations.

Abstract

Alumanyl silanides represent a rare class of main group complexes, characterized by an anionic Al-Si bond, stabilized through an intimate ion pair. Computations revealed pronounced multiple-bond character in these alumanyl...

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Cite This Study

Ludwig et al. (2026) studied this question.

synapsesocial.com/papers/696b29a19396dd04f30d9856https://doi.org/10.1039/d5sc09910b
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