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February 2, 2026Luminescence0 citations

Development of Sulfur and Nitrogen‐Doped Fluorescent Carbon Quantum Dots for Hydroquinone Sensing

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MMMurli Dhar MitraDRDibya Ranjan RoutAKAditya Kumar

Key Points

  • The study aims to develop fluorescent carbon quantum dots for sensitive detection of hydroquinone.
  • Synthesize sulfur- and nitrogen-doped carbon quantum dots using hydrothermal method.
  • Characterize the dots using HRTEM, XRD, XPS, and fluorescence spectroscopy.
  • Test the sensing ability for hydroquinone through concentration-dependent fluorescence quenching.
  • Achieved a quantum yield of 43% for the carbon quantum dots.
  • Established a detection limit of 75 nM for hydroquinone with a linear response up to 40 μM.
  • Demonstrated stability of fluorescence under pH variation and UV irradiation.

Abstract

ABSTRACT This study reports a facile hydrothermal synthesis of fluorescent sulfur‐ and nitrogen‐doped carbon quantum dots (S‐N‐CQDs) using cost‐effective solid precursors such as L‐methionine, malonic acid, and ethylenediamine. The S‐N‐CQDs exhibited a high quantum yield of 43%, measured with quinine sulfate as the reference standard. Various characterizations using HRTEM, XRD, XPS, zeta potential analysis, UV–Vis spectroscopy, and fluorescence lifetime measurements. The S‐N‐CQD particles have a size range of 2–3.5 nm and a zeta potential of −24.4 mV. The fluorescence of S‐N‐CQDs remained stable across a broad range of pH and under continuous UV irradiation (365 nm). Further S‐N‐CQDs were successfully employed as a fluorescent probe for hydroquinone (HQ) detection, showing concentration‐dependent fluorescence quenching. The probe demonstrated a detection limit of 75 nM, with a linear response in the range 10–40 μM ( R 2 = 0.998), and exhibited excellent selectivity toward HQ. The application and reliability associated with fluorescent probes were demonstrated for the examination of HQ in real water samples. The results found that the one‐pot hydrothermal synthesis method shows high sensitivity, selectivity, and accuracy for the detection of HQ, highlighting its potential for environmental monitoring and practical applications.

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Cite This Study

Mitra et al. (2026) studied this question.

synapsesocial.com/papers/6980fd9dc1c9540dea80f519https://doi.org/10.1002/bio.70431
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