Earth-abundant nickel phosphide electrocatalysts show great potential for the hydrogen evolution reaction (HER), yet their efficiency requires further enhancement for practical applications. Herein, a novel in situ strategy is developed to synthesize a high-performance electrocatalyst on nickel foam (NF), composed of N-doped carbon-coated Ni5P4–Ni3P heterostructures. This is achieved through the phosphidation and subsequent carbon coating of hydrothermally grown Ni(OH)2 nanosheets. The resulting catalyst exhibits excellent HER activity in acidic media, requiring a low overpotential of only 63 mV to achieve a current density of 10 mA cm−2. The superior performance stems from the synergistic effects of multiple factors: the porous nanosheet architecture and multi-phase interfaces provide abundant active sites, while the conductive N-doped carbon network significantly enhances charge-transfer kinetics and catalyst stability. This work presents an effective approach for designing efficient non-precious metal HER electrocatalysts.
Tang et al. (Fri,) studied this question.