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February 2, 2026Химия высоких энергий / High Energy Chemistry

Kinetic Regularities of Plasma-Solution Synthesis of Nickel Oxide

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KSK. V. Smirnova

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Overview

Research studies the kinetics of nickel hydroxocompound formation in aqueous solutions, indicating important mechanisms for synthesis.

Key Points

  • This research aims to understand the kinetics of nickel hydroxocompound formation in aqueous solutions under electrical discharge conditions.
  • Examined the formation of colloidal nickel compounds using direct current discharge in Ni(NO) • 6HO solutions.
  • Tested solution concentrations ranging from 20-60 mmol/L and discharge currents of 20-60 mA.
  • Determined reaction kinetics and energy efficiency of ion conversion.
  • Utilized X-ray diffraction to analyze precipitate composition.
  • Identified that colloidal systems form only when the solution acts as anode, not cathode.
  • Kinetics of nickel ion concentration loss follows zero/first order kinetics, independent of discharge current.
  • Conversion degrees ranged from 4-25%, energy efficiency was 0.1-0.5 ions per 100 eV.
  • Post-calcination, precipitates were confirmed as crystalline β-NiO.

Cite This Study

K. V. Smirnova (2025) studied this question.

synapsesocial.com/papers/6980fecbc1c9540dea8112achttps://doi.org/10.7868/s3034608825020094
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