What question did this study set out to answer?

To explore the use of sulfonyl hydrazones as electrophilic sulfur sources in nickel-catalyzed C-S coupling.

February 6, 2026Organic Letters

Redox-Active Sulfonyl Hydrazones as Programmable Sulfur Transfer for Nickel-Catalyzed C–S Coupling with Organic Halides

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Shows effective sulfur transfer in C-S coupling using sulfonyl hydrazones, indicating new synthetic pathways.

To explore the use of sulfonyl hydrazones as electrophilic sulfur sources in nickel-catalyzed C-S coupling.
Employ nickel-catalyzed reactions with a variety of organic halides.
Conduct mechanistic studies on the reaction pathway.
Investigate the roles of SO2R groups and manganese in the catalytic cycle.
Successful formation of C-S bonds with minimal C-C coupling products.
Key electrophilic sulfur species identified during the process.
Favorable reduction of sulfonyl hydrazones enhances reaction efficiency.

Yang et al. (2026) studied this question.

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February 6, 2026Organic Letters

View Full Paper

Ask AI

Bookmark

Authors

Shows effective sulfur transfer in C-S coupling using sulfonyl hydrazones, indicating new synthetic pathways.

To explore the use of sulfonyl hydrazones as electrophilic sulfur sources in nickel-catalyzed C-S coupling.
Employ nickel-catalyzed reactions with a variety of organic halides.
Conduct mechanistic studies on the reaction pathway.
Investigate the roles of SO2R groups and manganese in the catalytic cycle.
Successful formation of C-S bonds with minimal C-C coupling products.
Key electrophilic sulfur species identified during the process.
Favorable reduction of sulfonyl hydrazones enhances reaction efficiency.

Yang et al. (2026) studied this question.

View Full Paper

Ask AI

Bookmark