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February 6, 2026Chemical Communications0 citations

Solvent- and Heat-Induced Polymorphic Transformation with Single-Crystal Integrity in Cu(II) Paddle Wheel Metal Complexes

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GBGeetha BollaRMRaghavender Medishetty

Key Points

  • The aim is to explore the single-crystal-to-single-crystal transformation of a Cu(II) complex and identify new polymorphs.
  • Investigated the transformation of the Cu(II) paddle wheel complex
  • Utilized solvent and heat treatments to induce changes
  • Characterized the resultant polymorphs through crystallography.
  • Identified two novel polymorphs of the Cu(II) complex
  • Demonstrated successful single-crystal-to-single-crystal transformation
  • Results highlight the role of solvent and heat in polymorphic behavior.

Abstract

We report the single-crystal-to-single-crystal (SCSC) transformation of the Cu(II) paddle wheel complex Cu2(benzoate)4(24F-4spy)2 involving two novel polymorphs from form II to form I driven by both through solvent induced and...

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Cite This Study

Bolla et al. (2026) studied this question.

synapsesocial.com/papers/6985852f8f7c464f230085fchttps://doi.org/10.1039/d6cc00385k
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