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February 8, 2026Spectroscopy Journal0 citationsOpen Access

Esquel Meteorite, a Forgotten Argentine Peridot: A Multi Analytical Study

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FGFaramarz S. GardRARogelio Daniel AcevedoPGP. Gaztañaga

Key Points

  • This research aims to understand the formation and thermal evolution of the Esquel pallasite through multi-analytical techniques.
  • Characterization of a single Esquel specimen using SC-XRD, Raman spectroscopy, SEM-EDS, XPS, magnetic force microscopy, and X-ray computed tomography.
  • Quantitative analysis of Ni zoning through interface-to-center gradients and a width-center-Ni correlation method.
  • Identification of interconnected metal networks and micro-porosity via CT analysis.
  • Olivine grains were found to be structurally pristine, with confirmed crystallographic refinement.
  • XPS revealed a chemically unaltered silicate surface composed of lattice O2−, Si4+, Mg2+, and Fe2+.
  • Quantitative Ni zoning indicated a cooling rate of approximately 10–20 °C/Myr.
  • Magnetic force microscopy showed microscale magnetic structures correlating with chemical zoning in Fe–Ni.
  • CT analysis identified interconnected metal networks and inclusion structures consistent with melt migration.

Abstract

The Esquel pallasite provides a valuable record of metal–silicate interaction in differentiated planetesimals, yet many aspects of its formation and thermal evolution remain uncertain. Here, we present a comprehensive multi-technique characterization of a single Esquel specimen, integrating SC-XRD, Raman spectroscopy, SEM–EDS, XPS, magnetic force microscopy, and X-ray computed tomography. Olivine grains are shown to be structurally pristine, with the first full crystallographic refinement for Esquel confirming a single-domain silicate lattice. XPS demonstrates a stoichiometric silicate surface containing only lattice O2−, Si4+, Mg2+, and Fe2+, indicating that olivine remained chemically unaltered. The Fe–Ni metal preserves diffusion-controlled taenite–kamacite exsolution, compositionally distinct plessite, accessory schreibersite and troilite as resolved by SEM. Quantitative Ni zoning, evaluated through interface-to-center gradients and a width–center-Ni correlation method, yields a self-consistent cooling rate of ~10–20 °C/Myr. MFM reveals microscale magnetic structures that correlate directly with Fe–Ni chemical zoning, providing magnetic confirmation of slow cooling. CT analysis further identifies interconnected metal networks, inclusions, and micro-porosity reflecting melt migration and late-stage modification. These results establish Esquel as an exceptionally well-preserved pallasite and demonstrate the value of integrated, multi-scale analytical workflows for reconstructing early Solar System processes.

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Cite This Study

Gard et al. (2026) studied this question.

synapsesocial.com/papers/698828410fc35cd7a8847a78https://doi.org/10.3390/spectroscj4010003
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