The Mahai Basin (MHB), situated in the northern Qaidam Basin on the Qinghai–Tibetan Plateau, hosts significant Quaternary potash resources. Nevertheless, the sources and evolutionary pathways of potash-forming fluids remain controversial. In this study, a comprehensive multi-isotope dataset and online-first publications spanning the period from 2015 to 2025 were compiled to constrain the end-member characteristics and evolution of brines in the MHB. δD-δ18O indicates that the initial fluids were derived mainly from Qilian Mountains precipitation and snowmelt, delivered via surface runoff and concentrated through prolonged evaporation under arid, semi-closed conditions, forming a river-lake-brine evolution sequence. δ7Li (+7‰ to +40‰) systematically increases with salinity and K content, reflecting long-term low-temperature water–rock interactions and selective 6Li adsorption by secondary clays, while deep Ca-Cl brines represent highly evolved endmembers. Elevated 87Sr/86Sr ratios (0.7113–0.7122) confirm silicate weathering contributions, with intercrystalline brines acting as key intermediate end members. B, S, and Cl isotopes further highlight deep fluid ascent along faults and anticlines, driving K co-enrichment, while sandy–gravel brines inherit highly evolved paleo-lake signatures. These multi-isotope constraints define an integrated evolutionary model involving surface runoff recharge, evaporation-driven concentration with water–rock interaction, deep fluid mixing, lateral migration, and final potash precipitation.
Wang et al. (2026) studied this question.